Production Process Stages And Bioplastics Characterization From Corncob Waste
DOI:
https://doi.org/10.25181/jppt.v23i4.2691Abstract
Plastic is the dominant packaging used by the public, so it has the potential to damage the environment. It is necessary to synthesize raw materials for making plastics that are degraded by microorganisms, namely bioplastics. Bioplastics are packaging materials that are synthesized from natural raw materials so that they can be degraded in the environment. The raw material used is corncob because it is abundant and the benefits are not maximized. Research is needed to examine the stages of the production process and the characterization of bioplastics from corncob waste. The purpose of this study was to examine the stages of the production process and the characterization of bioplastics from corncob waste. This study used a laboratory experimental method with descriptive analysis. The production of bioplastics consists of the stages of making cellulose, cellulose acetate, and bioplastics using the solution casting method. The stages of cellulose isolation include hydrolysis, delignification, pulping, and bleaching, which showed an increase in cellulose content from 32.14% to 79.36%. Cellulose is acetylated to become cellulose acetate and has an acetyl content of 11.70 ± 0.40% with a yield of 121.16 ± 0.98%. The production of bioplastics uses a composition of cellulose acetate and chitosan at 50%:50% (w/w) successively. The resulting bioplastic has a thickness of 0.345 ± 0.024 mm, a density of 0.83 ± 0.03 g/cm3, a moisture content of 13.13%, a biodegradation value of 95.19%, a water resistance of 205.57%, and is transparent. The mechanical properties of bioplastics include a tensile strength of 22.3 N/m, an elongation of 21.11%, and a modulus of elasticity of 0.307 Mpa.Downloads
References
Aniriani, G.W. and Apriliani, N.F. (2017) ‘Perbandingan Yield Neraca Massa Hasil Pretreatment Tiga Jenis Limbah Lognoselulosa Dalam Memproduksi Polisakarida Menggunakan Teknik Kimiawi’, Jurnal Ilmiah Sains, 17(2), pp. 136–142.
Asparingga, H., Syahbanu, I. and Alimuddin, A.H. (2018) ‘Pengaruh Volume Anhidrida Asetat pada Sintesis Selulosa Asetat dari Sabut Kelapa’, Jurnal Kimia Khatulistiwa, 7(3), pp. 10–17.
Darmawan, M.T., Elma, M. and Ihsan, M. (2018) ‘Sintesis Dan Karakterisasi Selulosa Asetat Dari Alfa Selulosa Tandan Kosong Kelapa Sawit’, Jukung (Jurnal Teknik Lingkungan), 4(1), pp. 50–55. Available at: https://doi.org/10.20527/jukung.v4i1.4658.
Fatriasari, W., Masruchin, N. and Hermiati, E. (2019) Selulosa: Karakteristik dan Pemanfaatannya. Jakarta: LIPI Press.
Febrianti, R.P. (2019) ‘Pembuatan Bioplastik Berbahan Selulosa Asetat dari Tandan Kosong Kelapa Sawit dengan Penambahan Kitosan’, Departemen Teknologi Industri Pertanian Fakultas Teknologi Industri Pertanian [Preprint].
Fitriani, Bahri, S. and Nurhaeni (2013) ‘Produksi Bioetanol Tongkol Jagung ( Zea Mays ) dari Hasil Proses Delignifikasi’, Journal of Nature Science, 2(3), pp. 66–74.
Harpendi, R., Padil and Yelmida (2017) ‘Proses Pemurnian Selulosa Pelepah Sawit sebagai Bahan Baku Nitroselulosa dengan Variasi pH dan Konsentrasi H2O2’, Journal of Chemical Information and Modeling, 53(9), pp. 1689–1699. Available at: file:///C:/Users/User/Downloads/fvm939e.pdf.
Hasanah, Y.R. and Haryanto (2017) ‘Pengaruh Penambahan Filler Kalsium Karbonat (CaCO3) dan Clay Terhadap Sifat Mekanik dan Biodegradable Plastik dari Limbah Tapioka’, Techno, 18(2), pp. 96–107.
Luchese, C.L., Spada, J.C. and Tessaro, I.C. (2017) ‘Starch content affects physicochemical properties of corn and cassava starch-based films’, Industrial Crops & Products journal, 109(September), pp. 619–626. Available at: https://doi.org/10.1016/j.indcrop.2017.09.020.
Pratiwi, R., Rahayu, D. and Barliana, M.I. (2016) ‘Pemanfaatan Selulosa Dari Limbah Jerami Padi (Oryza sativa) Sebagai Bahan Bioplastik’, Indonesian Journal of Pharmaceutical Science and Technology, 3(3), p. 83. Available at: https://doi.org/10.15416/ijpst.v3i3.9406.
Rahmidar, L., Nurilah, I. and Sudiarty, T. (2018) ‘Karakterisasi Metil Selulosa yang Disintesis dari Kulit Jagung (Zea mays)’, PENDIPA Journal of Science Education, 2(1), pp. 117–122.
Roni, K.A. (2015) ‘Pembuatan Bioetanol dari Tanah Gambut dengan Proses Hidrolisis Asam Kuat’, Berkala Teknik, 5(1), pp. 801–813.
Saputro, A.N.C. and Ovita, A.L. (2017) ‘Sintesis dan Karakterisasi Bioplastik dari Kitosan-Pai Ganyong ( Canna edulis )’, Jurnal Kimia dan Pendidikan Kimia, 2(1), pp. 13–21.
Sari, D.S., Puri, W.A. and Hanum, D. (2019) Delignifikasi Bahan Lignoselulosa: Pemanfaatan Limbah Pertanian. CV. Penerbit Qiara Media.
Shao, X. et al. (2020) ‘Industrial Crops & Products Preparation and Characterization of Porous Microcrystalline Cellulose from Corncob’, Industrial Crops & Products journal, 151(April), pp. 1–6. Available at: https://doi.org/10.1016/j.indcrop.2020.112457.
Silitonga, N., Tarigan, N. and Saragih, G. (2018) ‘Pengaruh Konsentrasi NaOH pada Karakteristik α-Selulosa dari Pelepah Kelapa Sawit’, Jurnal Ready Star, (2013), pp. 103–108.
Souhoka, F.A. and Latupeirissa, J. (2018) ‘Sintesis dan Karakterisasi Selulosa Asetat (CA)’, Department of Chemistry, Faculty of Matemathic and Natural Sciences, Pattimura University, 5(2), pp. 58–62.
Suarni and Widowati (2007) ‘Jagung Teknik Produksi Dan Pengembangan’, Balai Penelitian Tanaman Serealia, pp. 410–426.
Surono, U.B. and Ismanto (2016) ‘Pengolahan Sampah Plastik Jenis PP , PET dan PE Menjadi Bahan Bakar Minyak dan Karakteristiknya’, Jurnal Mekanika dan Sistem Termal (JMST), 1(April), pp. 32–37.
Suryati, Meriatna, M. (2016) ‘Optimasi Proses Pembuatan Bioplastik dari Pati Limbah Kulit Singkong’, Jurnal Teknologi Kimia Unimal, 1, pp. 78–91.
Wahyusi, K.N., Siswanto and Utami, L.I. (2017) ‘Kajian Proses Asetilasi terhadap Kadar Asetil Selulosa Asetat dari Ampas Tebu’, Jurnal Teknik Kimia, 12(1), pp. 35–39.
Wijayanti, K.P. et al. (2016) ‘Bio-Degradable Bioplastik sebagai Plastik Ramah Lingkungan’, Surya Octagon Interdisciplinary Journal of Technology, 1(2), pp. 131–153.
Winarso, B. (2012) ‘Prospek dan Kendala Pengembangan Agribisnis Jagung di Propinsi Nusa Tenggara Barat Prospects and Constraints Agricultural Development of Corn in West Nusa Tenggara Province Bambang Winarso’, Jurnal Penelitian Pertanian Terapan, 12(2), pp. 103–114.
Wiradipta, I.D.G.A. (2017) ‘Pembuatan Bioplastik Biodegradable Berbahan Dasar Selulosa dari Tongkol Jagung’, Departemen Fisika, Institut Teknologi Sepuluh November [Preprint].
Zhaafirah, H., Fitriyano, G. and Hasyim, U.H. (2017) ‘Pengaruh Kecepatan Pengadukan Terhadap Rendemen dan Identifikasi Selulosa Asetat Hasil Asetilasi dari Limbah Kulit Pisang Kepok’, Jurnal Universitas Muhammadiyah Jakarta, (November), pp. 1–2.
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